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Kinetics and mechanism of silver Catalysed oxidation of Acetamide by bat

Author:

Vikram R Patil and Gaikwad, R.R.

Subject Area:

Physical Sciences and Engineering

Abstract:

The kinetics of Ag+ catalysed oxidation of Acetamide by N-bromoparatoluensulphonamide (BAT) as a oxidant is used. In aquous medium the reaction was carried out. Results from the study shows reaction was found to be of first order with respect to BAT and Acetamide. The specific rate of the reaction increases with an increase in BAT concentration as well as amide concentration, The specific rate is not affected by the addition of allyl acetate, Sodium chloride, PTS and by changing pH. The reaction rate remains constant and at the end the rate of reaction found to be first order. On the basis of these kinetic results, a possible reaction mechanism is proposed and an attempt has also been made to formulate a reaction scheme.

PDF file:

13606.pdf

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