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Synthesis and characterization of cu(ii), cd(ii) and pb(ii)complexes with tridentate s,n,o donor schiff base: interaction with human serum albumin (hsa) with cu(ii) complex

Author: 
Animesh Patra, Akhil Pandey and Surajit Maity
Subject Area: 
Physical Sciences and Engineering
Abstract: 

Metal complexes of Schiff base derived from 2-amino thiophenol and 2-hydroxy napthaldehyde (HL) have been synthesized and characterised by elemental analysis (C,H,N), infrared, electronic spectroscopic tools. The complexes are found to have the formula [ML(H2O)] where M is Cu(II), Cd(II), Pb(II). The interaction of Cu(II) complex towards Human Serum Albumin (HSA) was examined with the help of electronic spectroscopic tools. The electron transfer mechanism of copper (II) complex examined by cyclic voltammetry and indicate copper (II) complex gives Cu(II)/Cu(I) couple. Antibacterial activities of the complexes were studied by agar disc diffusion method and exhibited significant activities against gram-positive and gram-negative bacteria.

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