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Kinetics of vapor phase ammoxidation of o-xylene on v-sb-bi-zr/-al2o3 oxide catalyst i. about the competing ways of formation of the main products

Author:

Bagirzade, G. A., Tagiyev, D. B. and Manafov, M. R.

Subject Area:

Physical Sciences and Engineering

Abstract:

Kinetic regularities of vapor ammoxidation of xylene on the V-Sb-Bi-Cr / γ-Al2O3-oxide catalyst in the temperature range 648-708K are studied. It is shown that the formation of the phthalimide occurs both directly from o-xylene and in parallel through tolunitrile phthalonitrile. It is determined that the carbon dioxide formed by oxidation of o-xylene and decarboxylation of phthalimide, and benzonitrile from o-tolunitrile, and phthalimide.

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