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Microwave-assisted benzylic c-h activation using ruthenium catalysts. Synthesis of -lactams

Author:

Alexandra G. Sandor and Faïza Diaba

Subject Area:

Life Sciences

Abstract:

An expeditious synthesis of -lactams from benzyl-tethered trichloroacetamides using ruthenium catalysts in toluene under microwave activation was achieved. The new C(sp3)-C(sp3) bond formation takes place through a “Ru”complex promoted activation of a benzylic position in a radical process.

PDF file:

36548.pdf

DOI: https://doi.org/10.24941/ijcr.36548.09.2019

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