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Synthesis and characterization of copper (ii) nickel (ii), cobalt(ii), zinc(ii), tin(iv) and cadmium(ii) complexes with ferrocenyl phenylnthiosemicarbazones

Author:

Shalini Gupta, Neeraj Kumar, Saurabh Sharma and Ruchi Mishra

Subject Area:

Social Sciences and Humanities

Abstract:

A few complexes of copper(II), nickel(II), cobalt(II), Zinc(II), tin(IV) and cadmium(II) with two newly synthesized organometallic compounds, 1Formylferrocene phenylNthiosemicarbazone (HFfptsc) and 1acetyl ferrocene phenyl Nthiosemicarbazone (HAfptsc) have been isolated. The interaction of (HFfptsc) with Me2SnCl2 and MeSnCl3. Yield a series of organotin (IV) compounds. The reactivity of MeSn(Ffptsc)2Cl towards MeSH, Me2N SiMe3, Me2NsiMe3, SiMe3N3, and Me3SiCCPh are also described. These complexes have been characterized on the basis of elemental analysis, molecular weights, molar conductances, magnetic moments and spectroscopic (IR, 1HNMR, UVvis) data.

PDF file:

27412.pdf

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